Lead acid batteries continue to hold a leading position, especially in wheeled mobility and stationary applications. This strong market appeal entices manufacturers to explore ways to make the batteries better. Improvements have been made and some claims are so promising that one questions the trustworthiness. It is no secret that researchers prefer publishing the positive attributes while keeping the negatives under wraps. The following information on lead acid developments was obtained from available printed resources at the time of writing.
The composite plate material of the Firefly Energy battery is based on a lead acid variant that is lighter, longer living and has higher active material utilization than current lead acid systems. The battery includes foam electrodes for the negative plates, which gives it a performance that is comparable to NiMH but at lower manufacturing costs. Design concerns include microtubule blockage through crystal growth during low charge conditions. In addition, crystal expansion causes a reduction of the surface area, which will result in lower capacity with aging. Pricing is also a concern. It currently costs about $450 to manufacture a Firefly battery as opposed to $150 for a regular lead acid version. Firefly Energy is a spin-off of Caterpillar and went into bankruptcy in 2010.
Similar to the Firefly Energy battery, the Altraverda battery is based on lead. It uses a proprietary titanium sub-oxide ceramic structure, called Ebonex®, for the grid and an AGM separator. The un-pasted plate contains Ebonex® particles in a polymer matrix that holds a thin lead alloy foil on the external surfaces. With 50–60Wh/kg, the specific energy is about one-third larger than regular lead acid and is comparable with NiCd. Based in the UK, Altraverda works with East Penn in the USA, and the battery is well suited for higher voltage applications.
The Axion Power e3 Supercell is a hybrid battery/ultracapacitor in which the positive electrode consists of standard lead dioxide and the negative electrode is activated carbon, while maintaining an assembly process that is similar to lead acid. The Axion Power battery offers faster recharge times and longer cycle life on repeated deep discharges than what is possible with regular lead acid systems. This opens the door for the start-stop application in micro-hybrid cars. The lead-carbon combination of the Axion Power battery lowers the lead content on the negative plate, which results in a weight reduction of 30 percent compared to a regular lead acid. This, however, also lowers the specific energy to 15–25Wh/kg instead of 30–50Wh/kg, which a regular lead acid battery normally provides.
The CSIRO Ultrabattery combines an asymmetric ultracapacitor and a lead acid battery in each cell. The capacitor enhances the power and lifetime of the battery by acting as a buffer during charging and discharging, prolonging the lifetime by a factor of four over customary lead acid systems and producing 50 percent more power. The manufacturer also claims that the battery is 70 percent cheaper to produce than current hybrid electric vehicle (HEV) batteries. CSIRO batteries are undergoing road trials in a Honda Insight HEV and show good results. Furukawa Battery in Japan licensed the technology. The CSIRO battery is also being tested for start-stop applications in micro-hybrid cars to replace the lead acid starter battery. This battery promises extended life when exposed to frequent start-stop conditions and is able to take a fast charge.
This is the mystery battery/ultracapacitor combination that receives much media attention. The battery is based on a modified barium titanate ceramic powder and claims a specific energy of up to 280Wh/kg, higher than lithium-ion. The company is very secretive about their invention and releases only limited information. Some of their astonishing claims are: One-tenth of the weight of a NiMH battery in a hybrid application, no deep-cycle wear-down, three- to six-minute charge time, no hazardous material, similar manufacturing costs to lead acid, and a self-discharge that is only 0.02 percent per month, a fraction of that of lead acid and Li-ion.
Text taken from batteryuniversity.com